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The Archean Eon ( , also spelled Archaean or Archæan), in older sources sometimes called the Archaeozoic, is the second of the four of 's history, preceded by the and followed by the and the . The Archean represents the time period from (million years ago). The Late Heavy Bombardment is hypothesized to overlap with the beginning of the Archean. The Huronian glaciation occurred at the end of the eon.

The Earth during the Archean was mostly a : there was continental crust, but much of it was under an deeper than today's oceans. Except for some rare relict crystals, today's oldest continental crust dates back to the Archean. Much of the geological detail of the Archean has been destroyed by subsequent activity. The Earth's atmosphere was also vastly different in composition from today's: the prebiotic atmosphere was a reducing atmosphere rich in methane and lacking free .

The earliest known life, mostly represented by shallow-water called , started in the Archean and remained simple ( and ) throughout the eon. The earliest processes, especially those by early , appeared in the mid/late Archean and led to a permanent chemical change in the ocean and the atmosphere after the Archean.


Etymology and changes in classification
The word Archean is derived from the Greek word arkhē (), meaning 'beginning, origin'. The had been believed to be without life (azoic); however, fossils were found in deposits that were judged to belong to the . Before the Hadean Eon was recognized, the Archean spanned Earth's early history from its formation about 4,540 million years ago until 2,500 million years ago.

Instead of being based on , the beginning and end of the Archean Eon are defined chronometrically. The eon's lower boundary or starting point of 4,031±3 million years ago is officially recognized by the International Commission on Stratigraphy, which is the age of the oldest known intact rock formations on Earth. Evidence of rocks from the preceding Hadean Eon are therefore restricted by definition to non-rock and non-terrestrial sources such as individual mineral grains and lunar samples.


Geology
When the Archean began, the Earth's heat flow was nearly three times as high as it is today, and it was still twice the current level at the transition from the Archean to the Proterozoic (2,500 ). The extra heat was partly remnant heat from planetary accretion, from the formation of the metallic core, and partly arose from the decay of elements. As a result, the Earth's mantle was significantly hotter than today.

Although a few mineral grains have survived from the , the oldest rock formations exposed on the surface of the Earth are Archean. Archean rocks are found in Greenland, Siberia, the , Montana, Wyoming (exposed parts of the ), Minnesota (Minnesota River Valley), the , the Rhodope Massif, Scotland, India, Brazil, western Australia, and southern Africa. rocks predominate throughout the crystalline remnants of the surviving Archean crust. These include great melt sheets and voluminous masses of , , layered intrusions, and known as . Archean rocks are often heavily metamorphosed deep-water sediments, such as , , volcanic sediments, and banded iron formations. activity was considerably higher than today, with numerous lava eruptions, including unusual types such as . rocks are rare, indicating that the oceans were more acidic, due to dissolved , than during the Proterozoic.

(1986). 9780675201407, Merrill Publishing Company. .
are typical Archean formations, consisting of alternating units of metamorphosed igneous and sedimentary rocks, including Archean felsic volcanic rocks. The metamorphosed igneous rocks were derived from volcanic , while the metamorphosed sediments represent deep-sea sediments eroded from the neighboring island arcs and deposited in a basin. Greenstone belts, which include both types of metamorphosed rock, represent sutures between the protocontinents.
(1999). 9780716728825, W.H. Freeman and Company.

likely started vigorously in the , but slowed down in the Archean. The slowing of plate tectonics was probably due to an increase in the viscosity of the mantle due to outgassing of its water. Plate tectonics likely produced large amounts of continental crust, but the deep oceans of the Archean probably covered the continents entirely. Only at the end of the Archean did the continents likely emerge from the ocean. The emergence of continents towards the end of the Archaean initiated continental weathering that left its mark on the oxygen isotope record by enriching seawater with isotopically light oxygen.

Due to recycling and metamorphosis of the Archean crust, there is a lack of extensive geological evidence for specific continents. One hypothesis is that rocks that are now in India, western Australia, and southern Africa formed a continent called Ur as of 3,100 Ma. Another hypothesis, which conflicts with the first, is that rocks from western Australia and southern Africa were assembled in a continent called as far back as 3,600 Ma. Archean rock makes up only about 8% of Earth's present-day continental crust; the rest of the Archean continents have been recycled.

By the , plate tectonic activity may have been similar to that of the modern Earth, although there was a significantly greater occurrence of resulting from a hotter mantle, weaker plates, and increased tensile stresses on plates due to their crustal material metamorphosing from into as they sank. There are well-preserved sedimentary basins, and evidence of , intracontinental , continent-continent collisions and widespread globe-spanning suggesting the assembly and destruction of one and perhaps several . Evidence from banded iron formations, beds, chemical sediments and demonstrates that liquid water was prevalent and deep oceanic basins already existed.

Asteroid impacts were frequent in the early Archean. Evidence from layers suggests that impacts continued into the later Archean, at an average rate of about one impactor with a diameter greater than every 15 million years. This is about the size of the impactor. These impacts would have been an important oxygen sink and would have caused drastic fluctuations of atmospheric oxygen levels.


Environment
The Archean atmosphere is thought to have almost completely lacked free oxygen; oxygen levels were less than 0.001% of their present atmospheric level, with some analyses suggesting they were as low as 0.00001% of modern levels. However, transient episodes of heightened oxygen concentrations are known from this eon around 2,980–2,960 Ma, 2,700 Ma, and 2,501 Ma. The pulses of increased oxygenation at 2,700 and 2,501 Ma have both been considered by some as potential start points of the Great Oxygenation Event, which most scholars consider to have begun in the Palaeoproterozoic (). Furthermore, oases of relatively high oxygen levels existed in some nearshore shallow marine settings by the Mesoarchean. The ocean was broadly and lacked any persistent , a water layer between oxygenated and anoxic layers with a strong redox gradient, which would become a feature in later, more oxic oceans. Despite the lack of free oxygen, the rate of organic carbon burial appears to have been roughly the same as in the present. Due to extremely low oxygen levels, sulphate was rare in the Archean ocean, and sulphides were produced primarily through reduction of organically sourced sulphite or through mineralisation of compounds containing reduced sulphur. The Archean ocean was enriched in heavier oxygen isotopes relative to the modern ocean, though δ18O values decreased to levels comparable to those of modern oceans over the course of the later part of the eon as a result of increased continental weathering.

Astronomers think that the Sun had about 75–80 percent of its present luminosity, yet temperatures on Earth appear to have been near modern levels only 500 million years after Earth's formation (the faint young Sun paradox). The presence of liquid water is evidenced by certain highly deformed produced by metamorphism of . The moderate temperatures may reflect the presence of greater amounts of greenhouse gases than later in the Earth's history. Extensive abiotic denitrification took place on the Archean Earth, pumping the greenhouse gas into the atmosphere. Alternatively, Earth's may have been lower at the time, due to less land area and cloud cover.


Early life
The processes that gave rise to life on Earth are not completely understood, but there is substantial evidence that life came into existence either near the end of the Hadean Eon or early in the Archean Eon.

The earliest evidence for life on Earth is of biogenic origin found in 3.7 billion–year-old metasedimentary rocks discovered in .

The earliest identifiable fossils consist of , which are formed in shallow water by . The earliest stromatolites are found in 3.48 billion-year-old discovered in Western Australia. Stromatolites are found throughout the Archean and become common late in the Archean. Cyanobacteria were instrumental in creating free oxygen in the atmosphere.

Further evidence for early life is found in 3.47 billion-year-old , in the of Western Australia. This mineral shows sulfur of as much as 21.1%, which is evidence of sulfate-reducing bacteria that metabolize sulfur-32 more readily than sulfur-34.

Evidence of life in the Late Hadean is more controversial. In 2015, biogenic carbon was detected in dated to 4.1 billion years ago, but this evidence is preliminary and needs validation.

Earth was very hostile to life before 4,300 to 4,200 Ma, and the conclusion is that before the Archean Eon, life as we know it would have been challenged by these environmental conditions. While life could have arisen before the Archean, the conditions necessary to sustain life could not have occurred until the Archean Eon.

Life in the Archean was limited to simple single-celled organisms (lacking nuclei), called . In addition to the domain , microfossils of the domain have also been identified. There are no known fossils from the earliest Archean, though they might have evolved during the Archean without leaving any. Fossil , indicative of eukaryotes, have been reported from Archean strata but were shown to derive from contamination with younger organic matter. No fossil evidence has been discovered for replicators such as .

Fossilized microbes from terrestrial microbial mats show that life was already established on land 3.22 billion years ago.

, a Mesoarchean-Neoarchean fossil from South Africa, may be the first evidence of macroscopic land life, however it is likely a microbial mat due to a lack of eukaryotic features.


See also

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